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Acyclic homoconjugated polyacetylenes

From the heats of hydrogenation of these acyclic homoconjugated polyacetylenes we were able to derive an additivity value of —69.8 kcal/mol for the contribution of an interior alkyne... [Pg.325]

Figure 9-6 Acyclic homoconjugated polyacetylenes synthesized as reference compounds (a) EtMgBr, then CuCl, then 8 (b) KOH, MeOH, 46% for 16 - 17, 54% for 17 -> 18 (c) EtMgBr then acetone, 77% (d) cone. HCl, Cu powder, CaCi, 71%. Figure 9-6 Acyclic homoconjugated polyacetylenes synthesized as reference compounds (a) EtMgBr, then CuCl, then 8 (b) KOH, MeOH, 46% for 16 - 17, 54% for 17 -> 18 (c) EtMgBr then acetone, 77% (d) cone. HCl, Cu powder, CaCi, 71%.
See other pages where Acyclic homoconjugated polyacetylenes is mentioned: [Pg.325]   
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Homoconjugate

Homoconjugation

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