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The regioselective Baeyer-Villiger oxidation of acyclic aliphatic ketones normally results in the insertion of oxygen next to the bulkier alkyl chain. Since methyl is a poor migrating group, a common use of this reaction is to reduce the chain length of methyl ketones 1 two carbons to provide alcohols, after hydrolysis. The ability to synthesize methyl ketones from acids and med l-sutetituted alkenes (equation... [Pg.676]

See other pages where Acyclic aliphatic Baeyer-Villiger reaction is mentioned: [Pg.676] [Pg.676]

See also in sourсe #XX -- [ Pg.7 , Pg.676 ]

See also in sourсe #XX -- [ Pg.7 , Pg.676 ]