Activation of molecular hydrogen by homogenous

Activation of Molecular Hydrogen by Homogeneous Catalysts S. W. Weller and G. A. Mills Catalytic Syntheses of Ketones... 

HOMOGENEOUS ACTIVATION OF MOLECULAR HYDROGEN BY FOUR-, FIVE-, AND SIX-COORDINATE TRANSITION METAL COMPLEXES. 

PdClJ , Rh(III) and Ru(III) act as homogeneous catalysts for reduction of FeClj by molecular hydrogen ° °. The kinetics of all three activation reactions fall into Class I. The Arrhenius parameters are... 

The interconversion of a- and 7r-allyl complexes has been observed by Kwiatek, Mador, and Seyler in the interesting homogeneous catalytic system of potassium pentacyanocobaltate(II), K3Co(CN)5 (46). This solution absorbs molecular hydrogen to form the active hydride species, Kj[Co (CN)jH]. Addition of butadiene to the hydride results in the formation of a [Pg.36]

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