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Actinium electronic structure

The electronic structure of the actinide series starts with actinium [Rn]... [Pg.229]

Electronic Structures. Almost all the physical properties and chemical behavior of the rare earth elements find a logical explanation in terms of their electronic structures. Scandium, yttrium, lanthanum, and actinium are the first members, respectively, of the first, second, third, and fourth transition sequences of elements. In other words, each such element marks the beginning of an inner building where a stable group of 8 electrons is expanding to a completed (or more nearly complete) group of IS. This situation is illustrated for the first transition sequence. [Pg.30]

Thus, the structures of the elements above radon (element 86) through uranium were written to show the addition of the next two electrons in the 7s shell for element 87 (francium) and element 88 (radium) and addition in the 6d shell for actinium, thorium, protactinium and uranium (Latimer and Hildebrand 1940 Richtmeyer and Kennard 1942 Taylor and Glasstone 1942). [Pg.3]

Actinium and thorium have no / electrons and behave like transition metals with a body-centered cubic structure of thorium. Neptunium and plutonium have complex, low-symmetry, room-temperature crystal structures and exhibit multiple phase changes with increasing temperature due to their delocalized 5/ electrons. For plutonium metal, up to six crystalline modifications between room temperature and 915 K exist. The / electrons become localized for the heavier actinides. Americium, curium, berkelium, and californium all have room-temperature, double hexagonal, close-packed phases and high-temperature, face-centered cubic phases. Einsteinium, the heaviest actinide metal available in quantities sufficient for crystal structure studies on at least thin films, has a face-centered cubic structure as typical for a divalent metal. [Pg.13]


See other pages where Actinium electronic structure is mentioned: [Pg.216]    [Pg.16]    [Pg.261]    [Pg.235]    [Pg.216]    [Pg.217]    [Pg.71]    [Pg.216]    [Pg.217]    [Pg.12]    [Pg.17]    [Pg.19]    [Pg.8]    [Pg.33]    [Pg.247]    [Pg.259]    [Pg.362]    [Pg.80]    [Pg.128]    [Pg.43]    [Pg.186]    [Pg.15]    [Pg.158]    [Pg.235]    [Pg.6]    [Pg.16]    [Pg.161]    [Pg.260]   
See also in sourсe #XX -- [ Pg.337 ]




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