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Actinide complexes sulfides

Phosphine sulfides, selenides. Phosphine sulfides and selenides do not often act as Lewis bases towards tetravalent actinides, owing to their propensity for chalcogen transfer. Only the thorium complex ThCl4(SePPh3)2 has been reported. ... [Pg.230]

E4.36 Since the tri valent lanthanides and actinides (f-block elements) are found as complexes with hard oxygen bases (i.e., silicates) and not with soft bases such as sulfide, they must be hard. Since they are found exclusively as silicates, they must be considered very hard, unlike the borderline behaviour of Zn(II) (see Exercise 4.33 as well). [Pg.56]

See other pages where Actinide complexes sulfides is mentioned: [Pg.371]    [Pg.376]    [Pg.77]    [Pg.221]    [Pg.260]    [Pg.38]    [Pg.221]    [Pg.86]   
See also in sourсe #XX -- [ Pg.1135 ]

See also in sourсe #XX -- [ Pg.3 , Pg.1135 , Pg.1170 ]



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Sulfide complexes

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