Acoustic properties longitudinal mode

The acoustic properties of polymers are just as for many properties strongly dependent on temperature around the glass-rubber transition the sound speed decreases rapidly from a relatively high value at T < Tg to a relatively low value at T > Tg. During this transition the absorption shows a maximum value. An example is given in Fig. 14.4, where data for a poly(metacarborane siloxane) are displayed. The measurements were made in the longitudinal mode as a function of temperature at a frequency... 

Associated with each of the two modes of propagation, there is a sound speed and an absorption. Thus, four parameters are required to specify the acoustic properties of a solid isotropic polymer longitudinal speed, shear speed, longitudinal absorption, and shear absorption. 

Raman spectral-band frequencies for poly (thietane) as a crystallized melt annealed at 62° satisfy the rules for a longitudinal acoustic-mode frequency for deducing thickness. The morphology and physical properties of isoprene thietane block copolymers have been studied. Potential energies have been calculated for helical- and glide-type conformations of poly (thietane), and the conformations of the homopolymer have been calculated. ... 

ANL s ultrasonic viscometer is a nonintrusive in-line device that measures both fluid density and viscosity. The design of the viscometer is based on a technique that measures acoustic and shear impedance. The technique was first applied by Moore and McSkimin (1970) to measure dynamic shear properties of solvents and polystyrene solutions. The reflections of incident ultrasonic shear (1-10 MHz) and longitudinal waves (1 MHz), launched toward the surfaces of two transducer wedges that are in contact with the fluid, are measured. The reflection coefficients, along with the speed of sound in the fluid, are used to calculate fluid density and viscosity. Oblique incidence was commonly used because of better sensitivity, but mode-converted waves often occur in wedges that do not exhibit perfect crystal structure and lack well-polished surfaces. For practical applications, we use the normal-incidence arrangement. 

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