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Acidity of a-hydrogen atoms enolate formation

Bases can abstract a-protons from carbonyl compounds to form enolate [Pg.136]

Carbonyl compounds are more acidic than, for example, alkanes because the anion can be stabilised by resonance (see Section 4.3.1). [Pg.136]

3-Diketones (or 3-diketones) are therefore more acidic than water (which has a pKa-value of 16), as the enolate is stabilised by resonance over both carbonyl groups. [Pg.136]


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A-Hydrogen acidity

A-Hydrogen atom

A-enolation

Acidic hydrogen atom

Acidity of a-hydrogen atoms enolate ion formation

Acidity of a-hydrogens

Acidity of enols

Atoms, formation

Enol formate

Enol formation

Enolate formation

Enolates formation

Enolic acids

Enols acidity

FORMATION OF ENOLATES

Formation of hydrogen

Hydrogen atom formation

Hydrogen formation

Hydrogenation formation

Hydrogenation of acids

Hydrogenations formate

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