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Acid hydrolysis kinetics complex cleavages

The kinetics of aquation and base hydrolysis of the cis-[Co(en)2(NH2Et)02CR] ions (R = H or Me) have been studied in detail. Aquation is strongly acid-catalyzed and rate and activation parameters for this process are reported. Similar rates are observed for both complexes in spite of the differences in basicity of coordinated formate and acetate. Aquation rates (k q) are also very similar, but base hydrolysis of the formato complex is some five times faster than that of the acetato complex, consistent with a dissociative SNiCB mechanism and cleavage of the Co—O bond. [Pg.161]

See other pages where Acid hydrolysis kinetics complex cleavages is mentioned: [Pg.146]    [Pg.156]    [Pg.39]    [Pg.154]    [Pg.464]    [Pg.6609]    [Pg.150]    [Pg.125]    [Pg.59]    [Pg.464]    [Pg.232]    [Pg.113]    [Pg.114]    [Pg.90]    [Pg.1000]    [Pg.150]    [Pg.240]    [Pg.47]    [Pg.74]    [Pg.257]    [Pg.2985]    [Pg.182]    [Pg.283]    [Pg.304]    [Pg.37]    [Pg.163]   
See also in sourсe #XX -- [ Pg.123 , Pg.124 , Pg.125 , Pg.126 , Pg.127 , Pg.128 , Pg.129 ]



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Acid hydrolysis kinetics

Acid hydrolysis kinetics complexes

Acidic cleavage

Cleavage acids

Complexation kinetics

Hydrolysis cleavage

Hydrolysis complexes

Kinetic acidity

Kinetic complexity

Kinetic hydrolysis

Kinetics complexes

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