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Acid effect in radiation grafting

TABLE I. Acid Effect in Radiation Grafting to Polyethylene using Styrene in Low Molecular Weight Alcohols.a... [Pg.247]

TABLE VI. Acid Effect in Radiation Grafting using Styrene in DMF, DMSO, Acetone, Dioxan, Chloroform and Hexane.0 ... [Pg.249]

The parameters which predominantly influence the acid effect in radiation grafting of styrene monomer to polyethylene film are the structure of solvent, the concentration of monomer and the dose rate. Because these three variables are inter-related, it is difficult to predict, a priori, the conditions required to yield an optimum in grafting. In this respect the type of solvent used is particularly important. [Pg.252]

Mechanism of Acid Effect in Radiation Grafting. In earlier studies (13,14,15,21) on the mechanism of the acid effect on radiation grafting of styrene (MH) in dioxan or methanol (SH) to cellulose(Cell-OH)the sequence of events depicted in Equations (1) - (9) was proposed to explain the phenomenon. Thus, cellulose can undergo bond... [Pg.149]

Acid Effects in Radiation Grafting of Styrene to Cellulose and Polypropylene... [Pg.212]

Fig. 1. Acid effect in radiation grafting of styrene to polypropylene film (isotactic, doubly oriented, 0.06 mm) in methanol and ethanol at dose rate of 4.5 x 10" rad/hr to... Fig. 1. Acid effect in radiation grafting of styrene to polypropylene film (isotactic, doubly oriented, 0.06 mm) in methanol and ethanol at dose rate of 4.5 x 10" rad/hr to...
J.L, Garnett, S.V, Jankiewicz and D.F, Sangster, Acid effects in radiation polymerisation and grafting reactions, JoRad. Phys.Chem, in press. [Pg.346]

Acid Effects in the Radiation Grafting of Monomers to Polymers, Particularly Polyethylene... [Pg.244]

Acid Effect in UV- and Radiation-Induced Grafting of Styrene to Cellulose... [Pg.141]

In the present work, further mechanistic data for the acid effect in both UV and gamma radiation systems are reported, particularly molecular weight studies on the species present in the grafting solutions. The significance of these acid effects in possible commercial applications of the resulting copolymers of cellulose is also briefly mentioned. [Pg.142]

It is thus possible to investigate the conditions under which common intermediates may exist in both grafting and homopolymerisation processes. The results in the following Tables I -VIII thus concern acid effects in the radiation homopolymerisation of styrene in dioxan. [Pg.146]

In the present paper, this acid effect will be compared with other recently discovered additives (19), in particular the polyfunctional acrylates, for the enhancement in radiation grafting. [Pg.210]

J.L. Garnett and R.S. Kenyon, Acid Effects in the styrene comonomer technique for radiation grafting to wool, J.Polym. Sci.Polym.Lett.Edo 15 421 (1977). [Pg.344]


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