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Acid chlorides alkylrhodium complexes

Acylation with Alkylrhodium(Il Complexes and Acid Chlorides... [Pg.397]

The reaction of the rhodium(l) complex (CXLV) and organolithium or organomagnesium compounds produces the alkylrhodiums (CXLVI). Oxidative addition of an acid chloride to this intermediate, followed by reductive elimination, leads to unsymmetrical ketones in good yields. The alkyirhodium (CXLVI) does not react with aldehydes, esters, or nitriles. An additional benefit is that the starting rhodium complex (CXLV) is regenerated in reusable form in the last step (Hegedus et al., 1973, 1975a). Reaction of... [Pg.131]

See other pages where Acid chlorides alkylrhodium complexes is mentioned: [Pg.451]    [Pg.452]    [Pg.451]    [Pg.452]    [Pg.451]    [Pg.452]   
See also in sourсe #XX -- [ Pg.450 ]

See also in sourсe #XX -- [ Pg.450 ]



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