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Acid-catalyzed cyclopropyl ring opening

Figure 17. Hypothetical mechanism for the acid-catalyzed cyclopropyl ring opening of cycloartenol. Figure 17. Hypothetical mechanism for the acid-catalyzed cyclopropyl ring opening of cycloartenol.
Acid-catalyzed cyclopropyl ring opening of cycloartenol, hypothetical mechanism, 78/,79 5-Adenosyl-L-methionine, binding model, 81,83/... [Pg.246]

Cycloadduct 212 is converted into the dihydrobenzofuran 213 when treated with boron trifluoride diethyl etherate in good yield <2000JA8155>. The formation of the dihydrobenzofuran proceeds by an initial ring opening followed by a subsequent dehydration and acid-catalyzed cyclopropyl ketone rearrangement (Equation 142). [Pg.1191]


See other pages where Acid-catalyzed cyclopropyl ring opening is mentioned: [Pg.240]    [Pg.340]    [Pg.183]    [Pg.89]    [Pg.773]    [Pg.235]    [Pg.300]    [Pg.61]    [Pg.773]    [Pg.299]    [Pg.376]    [Pg.699]    [Pg.158]    [Pg.89]    [Pg.26]    [Pg.261]    [Pg.257]    [Pg.276]    [Pg.190]    [Pg.132]   


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