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Achmatowicz oxidation rearrangement

The oxidation of furyl-2-carbinols can prodnce 6-hydroxy-2//-pyran-3(6//)-ones (the Achmatowicz rearrangement), which have several synthetic nses, the most important in the heterocyclic context being for the formation therefrom of pyrylinm-3-olate species (11.1.7). The oxidation can be condncted with meto-chloroperbenzoic acid, vanadinm(lll) acetylacetonate with f-butyl peroxide, or with singlet oxygen (18.7). [Pg.351]

See other pages where Achmatowicz oxidation rearrangement is mentioned: [Pg.16]    [Pg.130]    [Pg.312]    [Pg.16]    [Pg.130]    [Pg.312]    [Pg.156]    [Pg.333]    [Pg.15]    [Pg.130]    [Pg.498]    [Pg.102]    [Pg.22]    [Pg.109]   
See also in sourсe #XX -- [ Pg.16 ]



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