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Acetylene cyclobutenone synthesis

The synthesis of the cyclobutenone (313) has been accomplished by reaction of the acetylene (312) with dichloroketen. The potassium salt (314 R = K) of the diketo-enol (314 R = H), obtained by dilute HQ hydrolysis of the dichloroketen-ethoxyacetylene adduct (315), corresponds in structure to moniliformin, a new cyclobutenone microbial toxin. [Pg.70]


See other pages where Acetylene cyclobutenone synthesis is mentioned: [Pg.161]    [Pg.732]    [Pg.122]    [Pg.732]    [Pg.564]    [Pg.163]    [Pg.651]   
See also in sourсe #XX -- [ Pg.5 , Pg.689 ]




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