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Absolute configuration transition metal complexes

The absolute configuration of transition metal complexes. R. D. Gillard and P. R. Mitchell, Struct. Bonding (Berlin), 1970,7, 46-86 (165). [Pg.36]

Gillard RD, Mitchell PR (1970) The Absolute Configuration of Transition Metal Complexes. 7 46-86... [Pg.246]

For many years no attempt was made to determine the absolute stereochemistry of transition metal complexes, although Kuhn (8) calculated the absolute configuration of (—)n-[Co(C204)3]3- from its anomalous optical rotatory dispersion, using classical coupled oscillator theory. He later (9) extended his theory to other tris-chelated cobalt complexes such as (+)n-[Co(en)3]3+. However, in 1955 Saito (10) showed by anomalous X-ray dispersion that Kuhn s suggested configuration for (+)n-[Co(en)3]3+ was incorrect. [Pg.47]


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See also in sourсe #XX -- [ Pg.1518 , Pg.1519 , Pg.1520 , Pg.1521 ]




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