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A Non-Linear Approximation - Local Anisotropy

For the case, when the local anisotropy is taken into account, the relations (3.9) ought to be generalised as [Pg.45]

Introduction of the local anisotropy of mobility allows us to specify the matrixes of the extra forces of external and internal resistance and to formulate dynamic equations, which will be discussed in Section 3.4. One can expect that, as a result of the introduction of the local anisotropy, mobility of a particle along the axis of a macromolecule appears to be bigger than mobility in the perpendicular direction, so that the entire macromolecule can move more easily along its contour. The local anisotropy hinders also change of the form of the macromolecular coil, and, by this way, plays a role similar to the role of the term with internal resistance in linear version of the model. [Pg.46]


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A linear

Linear approximation

Linearized approximation

Local anisotropy

Local approximation

Non-local

Non-locality

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